Crystal Structure of (C-rac-1, 5, 8, 12-Tetramethyl-1, 4, 8, 11-tetraazacyclotetradecane-N, N, N", N)nickel(II) Tetrachlorozincate(II).
نویسندگان
چکیده
منابع مشابه
Diaqua(1,4,8,11-tetraazacyclotetradecane-κ4 N 1,N 4,N 8,N 11)copper(II) didecanoate dihydrate
The Cu(II) atom in the title salt, [Cu(C(10)H(24)N(4))(H(2)O)(2)][CH(3)(CH(2))(8)CO(2)](2)·2H(2)O, is chelated by the four N atoms of the 1,4,8,11-tetra-aza-cyclo-tetra-decane (cyclam) ligand and is coordinated by two water mol-ecules in a Jahn-Teller-type tetra-gonally distorted octa-hedral geometry. The Cu(II) atom lies on a center of inversion. The cations, anions and uncoordinated water mol...
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The title compound, [Cu(C(10)H(24)N(4))(H(2)O)(2)][CH(3)(CH(2))(10)CO(2)](2)·2H(2)O, consists of one cationic copper(II) complex, two dodeca-noate anions and two water solvent mol-ecules. The Cu(II) atom is located on an inversion center and is chelated by the four aza N atoms of the neutral 1,4,8,11-tetra-aza-cyclo-tetra-decane (cyclam) ligand and by two water mol-ecules in axial positions, gi...
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The Cu(II) atom in the title salt, [Cu(C(10)H(24)N(4))(H(2)O)(2)][CH(3)(CH(2))(5)CO(2)](2)·2H(2)O, is chelated by the four N atoms of the 1,4,8,11-tetra-aza-cyclo-tetra-decane (cyclam) ligand and is coordinated by two water mol-ecules in a tetra-gonally Jahn-Teller-distorted octa-hedral geometry. The Cu(II) atom lies on a center of inversion. The cations, anions and uncoordinated water mol-ecul...
متن کامل1 , 8 - bis ( 2 - hydroxy - 3 , 5 - di - tert - butylbenzyl ) - 4 , 11 - dibenzyl - 1 , 4 , 8 , 11 - tetraazacyclotetradecane
A cyclam (1,4,8,11-tetraazacyclotetradecane)-based macrocycle bearing two benzyl and two 2-hydroxy-3,5-di-tert-butylbenzyl pendent arms was synthesized and characterized using spectroscopic techniques and single crystal X-ray diffraction. The macrocycle crystallizes in the triclinic space group P-1, with the asymmetric unit containing one-half of the molecule. The structure is stabilized by hyd...
متن کاملthe crystal and molecular structure of n, n’-3, 6-dioxa-1, 8-octanebis (salicylaldimine), c20 h24 n2o24
the crystal structure of the compound c20 h24 n2 o24 was determined by direct methods. thecrystals are monoclinic, space group p21/n, and unit cell parameters are: a= 10.2342 (9), b=4.8763 (5),c=19.3578 (11) a, β =98.9632 (10) o ,v=956.6 (5) a3, z=2, dc=1.239grm-3, dm=1.22grm-3. the final rfactorsare converged to r=0.059 and rw=0.056 for 553 independent observed reflections. themolecules are li...
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ژورنال
عنوان ژورنال: Analytical Sciences
سال: 2000
ISSN: 0910-6340,1348-2246
DOI: 10.2116/analsci.16.437